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Volume 75 Issue 3-4 / 2004
Изотермна и неизотермна кинетика на твърдофазни реакции - математичен апарат и резултати
Isothermal and non-isothermal kinetics of solid state reactions. Mathematical apparatus and results
Автор(и): Л. Влаев
Author(s): L. Vlaev
Abstract: The present review describes the mathematical apparatus used for the study of solid phase reactions taking place under isothermal or non-isothermal heating. The algebraic forms of the equations model the specific mechanism of the rate-limiting stage of the process. Seven of the most often used calculation procedures are compared to each other. Based on own investigation of the thermal decomposition of different selenites, the values of the activation energy and pre-exponential factor in Arrhenius equation as well as the change of entropy for the formation of the activated complex by the reagent were found. It is shown that, by selecting the correct kinetic equations, there exists a kinetic compensation effect between the pre-exponential factor and the activation energy.
Keywords: Isothermal and non-isothermal kinetics; Solid-state reactions; Mathematical apparatus; Thermogravimetry.
Pages: 49 - 60 (12 pages)
Плазмени и електрохимични нанотехнологии
Plasma and electrochemical nanotechnologies
Автор(и): Г. Високов
Author(s): G. Vissokov
Abstract: This review presents own and literature considerations
and investigations about plasma nanotechnologies
in the field of plasmachemical synthesis of nanostructured
materials (nanopowders): metals, metal
oxides, nitrides, carbides, carbonitrides, pigments, catalysts,
sorbents, etc. The application of plasmachemical
nanostructured materials (powders, coatings,
modified surfaces) and the advantages and disadvantages
of the plasmachemical processes are discussed.
The present survey of nanoelectrochemical treatment
and modification of surfaces aimed at producing
and investigating nanomaterials allows the determination
of priority fields in fundamental and applied
research as well as the production of materials of
practical importance.
Keywords: Plasma- and electrochemical nanotechnology; Nanoscience; Researches; Applications.
Pages: 61 - 71 (11 pages)
Пета национална конференция по химия. Дискусия „Метрология в химията“
Автор(и): И. Хавезов
Д. Л. Цалев
Pages: 72 - 76 (5 pages)
Из историята на Съюза на химиците в България. Част 2
Автор(и): Н. Найденов
Pages: 77 - 80 (4 pages)
Новини
Юбилеи
Предстоящо
Нови книги
In memoriam
Pages: 81 - 104 (24 pages)